The thermal maturity of sedimentary basins as revealed by magnetic mineralogy     

Mansour M. Abdelmalak  Stéphane Polteau 《Basin Research》2020,32(6):1510-1531

The thermal evolution of sedimentary basins is usually constrained by maturity data, which is interpreted from Rock-Eval pyrolysis and vitrinite reflectance analytical results on field or boreholes samples. However, some thermal evolution models may be inaccurate due to the use of elevated maturities measured in samples collected within an undetected metamorphic contact aureole surrounding a magmatic intrusion. In this context, we investigate the maturity and magnetic mineralogy of 16 claystone samples from Disko-Svartenhuk Basin, part of the SE Baffin Bay volcanic margin. Samples were collected within thermal contact metamorphic aureoles near magma intrusions, as well as equivalent reference samples not affected by intrusions. Rock-Eval pyrolysis (T_max), and vitrinite reflectance (Ro) analysis were performed to assess the thermal maturity, which lies in the oil window when 435°C ≤ T_max ≤ 470°C and 0.6%–0.7% ≤ Ro ≤ 1.3%. In addition, we performed low- (<300K) and high-temperature (>300K) investigations of isothermal remanent magnetization to assess the magnetic mineralogy of the selected samples. The maturity results (0.37% ≤ Ro ≤ 2%, 22°C ≤ T_max ≤ 604°C) show a predominance of immature to early mature Type III organic matter, but do not reliably identify the contact aureole when compared to the reference samples. The magnetic assemblage of the immature samples consists of iron sulphide (greigite), goethite and oxidized or non-stoichiometric magnetite. The magnetic assemblage of the early mature to mature samples consists of stoichiometric magnetite and fine-grained pyrrhotite (<1 μm). These results document the disappearance of the iron sulphide (greigite) and increase in content of magnetite during normal burial. On the other hand, magnetite is interpreted to be the dominant magnetic mineral inside the contact aureole surrounding dyke/sill intrusions where palaeotemperatures indicate mature to over-mature state. Interestingly, the iron sulphide (greigite) is still detected in the contact aureole where palaeotemperatures exceeded 130°C. Therefore, the magnetic mineralogy is a sensitive method that can characterize normal burial history, as well as identify hidden metamorphic contact aureoles where the iron sulphide greigite is present at temperatures beyond its stability field.  相似文献   

西藏冈底斯岩带曲水杂岩体锆石LA-ICP-MS U-Pb年龄及其地质意义     

次琼  永忠拉达  阿旺旦增  次仁吉 《沉积与特提斯地质》2020,40(2):116-128

曲水杂岩体位于冈底斯构造-岩浆岩带东段南缘,其岩浆活动与雅鲁藏布江新特提斯洋壳向北俯冲、消减以及印度与欧亚板块碰撞息息相关。本文以曲水县-昌果乡广泛分布的中酸性花岗岩体为研究对象,进行了系统的LA-ICP-MS锆石U-Pb年代学和岩石地球化学研究。结果表明,曲水杂岩体由3期时代和规模不同的花岗质岩体构成,其LA-ICP-MS锆石U-Pb年龄分别为95.2±1.0～88.5±1.0Ma、65.2±0.6Ma和48.5±0.5～43.3±0.7Ma;岩石地球化学研究表明,晚白垩世和古新世花岗岩以中性-中酸性为主,属钙碱性系列,具中铝特征,A/CNK比值小于1.1,属于I型花岗岩,是玄武质下地壳部分熔融产物,指示其形成于特提斯洋壳俯冲过程的岛弧构造环境。始新世花岗岩以高钾钙碱性系列为主,并出现钾玄岩系列,具偏铝-过铝质特征,指示岩浆上侵过程中遭受了不同程度的地壳物质混染,其形成于印度-欧亚板块强烈碰撞的构造环境。  相似文献   

云南哀牢山-红河剪切带新生代富碱侵入岩中榍石年代学和地球化学特征     

马倩  杨岳衡  赵志丹  佟鑫  武精凯  苗壮  李晨  雷杭山 《岩石学报》2020,36(9):2751-2764

榍石作为副矿物在哀牢山-红河剪切带新生代富碱侵入岩中广泛存在。原位获取榍石矿物内部微量元素、U-Pb年龄和Sm-Nd同位素的空间变化对获取矿物和岩石的成因演化信息具有重要意义。本文使用四级杆/多接收电感耦合等离子体质谱(Quadrupole/Multi-Collector Inductively Coupled Plasma Mass Spectrometry,Q/MC-ICP-MS)与激光剥蚀系统(Laser Ablation,LA)联用,对哀牢山-红河剪切带5个富碱侵入岩体(桃花岩体、宁蒗-永胜岩体、哈播岩体、铜厂岩体和十里村岩体)中榍石开展了微区原位微量元素、U-Pb年代学和Sm-Nd同位素研究。微量元素分析结果表明,三江富碱侵入岩中榍石为岩浆成因,亏损Rb、Ba、Pb、Sr等大离子亲石元素,富集Th、U、Nb、Ta、Zr、Hf等高场强元素。榍石的稀土配分图均表现为明显右倾,不具有或具有弱的Eu负异常。与云南北衙、马厂箐矽卡岩矿床中的热液榍石相比,本文榍石在稀土元素组成上,具有较高的稀土元素总量、较高的Th/U、LREE/HREE和Ce/Ce*比值,具有较低的Eu/Eu*、Nb/Ta、Zr/Hf比值。微区原位LA-Q-ICP-MS U-Pb定年结果表明,研究区富碱岩体中榍石结晶年龄在32.5～37.9Ma之间,代表了岩体形成时代,与三江地区哀牢山-红河剪切带及其附近新生代富碱岩浆活动高峰期(～35Ma)一致,属于青藏高原晚碰撞期岩浆作用的产物。榍石微区原位LA-MCICP-MS Sm-Nd同位素分析结果显示,榍石颗粒的Nd同位素组成均一,表明榍石结晶过程中寄主岩浆的Nd同位素组成没有发生明显变化。各个富碱岩体之间的榍石Nd同位素组成变化范围在-6.8～-2.1之间,与全岩的同位素特征一致,表明榍石的原位微区Sm-Nd同位素可以作为富碱侵入岩研究中有效的示踪手段之一。  相似文献   

川西甲基卡矿床外围中酸性侵入岩LA-ICP-MS锆石U-Pb年龄及地球化学特征     

李名则  秦宇龙  赵春  詹涵钰  周雄  孙光银 《中国地质调查》2020,7(5):1-9

在川西甲基卡矿床外围新发现了建巴村中酸性侵入岩体,为了探讨其形成时代、成岩构造背景及其成矿条件,开展了LA-ICP-MC锆石U-Pb年代学和地球化学特征研究。结果表明: 该岩体的结晶年龄为(211.8±1.0) Ma; 岩石属于钙碱性-高钾钙碱性准铝质中酸性侵入岩系列,具有I型花岗岩类的特征,其物质来源可能为壳源物质与幔源物质部分熔融。地球化学特征表明其形成于后碰撞环境,与此时期内川西地区的区域性岩浆活动相对应。建巴村岩体的构造位置及岩浆活动特征指示其可能不具备形成伟晶岩矿床的条件。  相似文献   

In situ measurements of wind‐driven salt fluxes through constructed channels in a coastal wetland ecosystem          下载免费PDF全文

Alex K. Manda  Enrique Reyes  James M. Pitt 《水文研究》2018,32(5):636-643

A suite of instruments was deployed in a coastal wetland ecosystem in the Albemarle estuarine system, North Carolina (USA), to characterize wind‐driven transport of saltwater through a constructed (man‐made) channel. Flow velocity, electrical conductivity, and stage were measured in a representative channel over a 2‐month period from May to July 2014, during which 4 wind tides were observed. Collected data show that thousands of metric tons of salt were advected through the channel into coastal wetlands during each event, which lasted up to 4 days. The results reveal that as much as 36% of advected salts accumulated in the wetlands, suggesting that the cumulative effects of these events on the health of coastal wetlands in the Albemarle system may be substantial due to the abundance of constructed channels and the frequency of wind‐driven tidal events. This study is the first to quantify wind‐driven salt fluxes through constructed channels in coastal wetland settings.  相似文献   

Data-based modelling approach for variable density flow and solute transport simulation in a coastal aquifer   总被引：1，自引：1，他引：0  

Basant Yadav  Shashi Mathur  Sudheer Ch  Brijesh Kumar Yadav 《水文科学杂志》2018,63(2):210-226

Data-based models, namely artificial neural network (ANN), support vector machine (SVM), genetic programming (GP) and extreme learning machine (ELM), were developed to approximate three-dimensional, density-dependent flow and transport processes in a coastal aquifer. A simulation model, SEAWAT, was used to generate data required for the training and testing of the data-based models. Statistical analysis of the simulation results obtained by the four models show that the data-based models could simulate the complex salt water intrusion process successfully. The selected models were also compared based on their computational ability, and the results show that the ELM is the fastest technique, taking just 0.5 s to simulate the dataset; however, the SVM is the most accurate, with a Nash-Sutcliffe efficiency (NSE) ≥ 0.95 and correlation coefficient R ≥ 0.92 for all the wells. The root mean square error (RMSE) for the SVM is also significantly less, ranging from 12.28 to 77.61 mg/L.  相似文献   

高分异花岗岩浆可能是华南花岗岩型铀矿床主要铀源——来自诸广山南体花岗岩锆石铀含量的证据     

伍皓  夏彧  周恳恳  张建军 《岩石学报》2020,36(2):589-600

锆石的U-Pb测年、Hf和O同位素及稀土、微量元素的研究与应用已获得诸多进展,但锆石中铀含量所蕴藏的地质意义却较少被关注。华南花岗岩型铀矿床的铀源一直存在争议,不同观点认为其分别来自早期已固结地质体、分异岩浆、地幔柱或热点以及U、Th、K富集圈。为尝试利用锆石中的铀含量来追索铀源,本文通过搜集诸广山南体花岗岩锆石U-Pb同位素测年文献,掌握了该花岗岩中14个岩体、37件样品、3种岩性,共467个锆石定年数据。通过数据分析发现印支期(253Ma、244Ma)和燕山期(139Ma、124Ma)具高分异特征的4件酸性岩脉(小岩体)样品中锆石的铀含量明显高于同期岩体。依据铀矿床中高分异酸性岩脉(小岩体)侵位期、基性岩脉侵位期、铀成矿早期(140~90Ma)三者的良好对应关系,结合这一锆石铀含量指示,初步认为华南花岗岩型铀矿床中铀可能主要来自高分异花岗岩浆;推测花岗岩型铀成矿可能属壳幔混合作用结果,即铀源来自地壳分异岩浆,成矿流体和矿化剂主要来自地幔,而成矿空间受断裂系统控制。岩体锆石铀含量或可在铀源丰度、矿床品位判别等方面发挥积极作用。  相似文献   

湖南仁里超大型钽铌矿床工作进展及找矿思路     

杨世珍  周芳春  李建斌  刘翔  李建康  黄志飚  苏俊男  李鹏 《中国地质调查》2020,7(4):28-36

湖南仁里超大型钽铌矿床钽铌铍矿资源丰富,Ta₂O₅资源量达到了超大型规模,BeO资源量达到了大型规模。为进一步研究湖南仁里超大型钽铌矿床稀有金属的赋存特征、成矿规律及矿产资源综合利用前景,开展了地球化学分析、电子探针、包裹体、同位素测年及可选性试验等研究工作,通过系统梳理仁里超大型钽铌矿床的工作进展,进一步探讨了该矿床的下一步找矿思路。仁里钽铌矿床共(伴)生矿种多,稀有金属综合回收率及矿产资源采选综合利用率高,具有极大的开发利用价值,可作为绿色、环保、无尾矿范例进行高效勘查与开发。仁里矿区钽铌铍矿资源丰富,具有较好的找矿潜力,加大地质勘查资金投入有望取得钽铌铍锂等稀有金属找矿新进展。下一步应对矿区2、3、5、6号主矿脉深部矿体进行控制,力争取得钽铌铍矿找矿突破,同时加强对矿区西部或西南部隐伏锂辉石白云母钠长石伟晶岩的研究工作,力争取得锂辉石白云母钠长石伟晶岩型锂矿找矿突破。  相似文献   

State of seawater intrusion and its adaptive management countermeasures in Longkou City of China          下载免费PDF全文

ZHONG Hua-ping  WU Yong-xiang 《地下水科学与工程》2020,8(1):30-42

Longkou City is a coastal area,and lacks water resources.The overexploitation of groundwater causes seawater intrusion.At present,seawater intrudes an area of 68 km2.With the decrease of groundwater extraction,the seawater intrusion area has generally declined.The paper expounds the development process of seawater intrusion as well as the corresponding prevention and control measures of using groundwater replenishment and groundwater throttling in Longkou City.In view of the seawater intrusion problem in Longkou City,some adaptive management countermeasures are put forward,which include:Adjusting industrial and agricultural structure,promoting economic and social development to match water resources;improving water usage structure,optimizing the utilization of water resources;advancing the construction of a water-saving society,using water resources efficiently;implementing inter-basin water transfer,using water resources rationally;developing and utilizing unconventional water sources,making full use of water resources;strengthening water infrastructure construction,increasing the development and utilization potential of water resources;carrying out ecological restoration,protecting water resources and ecological environment;improving the management informationalization level,strengthening the capabilities of groundwater monitoring and management;increasing publicity,improving public awareness of participation.  相似文献   

云南金平县阿德博独居石矿床成矿时代及地质意义     

王炳华 《地质与勘探》2020,56(3):523-539

西南三江地区是我国重要的成矿区带之一,具有复合叠加成矿特征。阿德博独居石矿床位于云南省金平县境内,印度地块、哀牢山-金沙江断裂带南侧,属于哀牢山隆起的东南延伸部分。该矿床赋存于花岗质风化壳中,岩性主要有片麻状花岗岩、二长花岗岩、花岗片麻岩;矿体中主要含有独居石,少量磷钇矿、锆石、金红石、钛铁矿、榍石。岩体中片麻状花岗岩的锆石U-Pb谐和年龄为31.40±0.16Ma(MSWD=7.8),二长花岗岩的锆石U-Pb谐和年龄为34.52±0.22 Ma(MSWD=1.3),表明阿德博岩体形成于新生代古近纪,与三江地区构造体制转换阶段富碱斑岩体的成矿时期一致。片麻状花岗岩中45个锆石Hf同位素数据结果较均一,(~(176)Hf/~(177)Hf)i比值范围为0.282583～0.282712,平均为0.282633,εHf(t=31.40 Ma)范围为-6.00～-1.44,平均值为-4.21。二长花岗岩中13个锆石Hf同位素数据结果变化范围较大,(~(176)Hf/~(177)Hf)i=0.282484～0.282814(平均值为0.282681),εHf(t=31.40 Ma)=-9.43～2.22(平均值为-2.45);其中有8粒锆石的εHf(t)为负值,5颗锆石的εHf(t)为正值,暗示岩体的源区主要为地壳物质的部分熔融,可能有地幔物质的混合。  相似文献